pyper said:
(broken link removed to http://gaia.lbl.gov/btech/papers/12486.pdf)
Excellent! Thank you for locating that. :coolsmile:
Page 6. It says that Argon has a thermal conductivity factor of 1.78 and Air is 2.5 -- so that makes Argon 140% better than air at slowing heat loss through the gap. This probably explains why every low-e window seems to have something other than air in the gap.
Math issue: The difference in thermal conductivity between air and argon = 2.5-1.78 = .72. The proportional reduction in thermal conductivity by going from air to argon = .72/2.5 = 0.288. Argon represents a reduction in thermal conductivitiy of 28.8% over air. Not too shabby, but not 140%.
But, more importantly, keep in mind the following from the paragraph at the end of page 5, before the table:
Table II gives some of the physical properties of gases that may be used in an architectural window. The variation in these properties over the range of ambient temperatures should be considered when doing detailed calculations. All of the gases listed have a lower thermal conductivity than air, which means they will perform better at small gap spacings where conduction is the dominant mode of heat transfer. Low conductivity is a necessary but not sufficient condition for their use; cost, chemical reactions with other window components and toxicity must also be considered.
I think we are coming to an interesting crossroad here. The small gap spacing typical of most multi-pane windows is clearly the best application for the low conductivity gas in the interstitial space,
because such a small space provides very little resistance to thermal conductivity! Continued with the next point . . .
On page 8 it shows what happens to the U value as air gap is increased from 0 to 5 cm, with zero, one, and two plastic films between. It shows that with double glazing the performance increases dramatically up to about 15mm, and after 2mm holds constant. This probably explains why there are no double glazed windows on the market with 2" air gaps.
Other than the typo above (after 20mm, not 2mm), you are highlighting exactly where I think this debate is going. A 5mm gap is only marginally effective compared to going with a 15mm+ air gap. A 20mm air gap is just over 3/4 of an inch, which is just about what the spacing was on my c.1990 Pella thermopane windows I installed in my newly constructed house that year. Over 1" is clearly a situation of diminishing returns. I think the data in that (old) paper shows that utilizing Ar or Kr is CRITICAL when choosing a small gap thermopane window. When a larger air gap is utilized, the efficacy of the reduced conductivity becomes a much smaller proportion of the overall efficiency of the window system. I also suspect the cost for the higher volume of gas becomes a substantial consideration. Combine the additional cost of the gas, with the architectural challenges of making a thermo-pane window with a gap larger than 3/4-1" and you have the reason why such windows are not offered in the mass market.
It appears to me that the choice between a low-e thermopane window with a small gap and argon, or a single pane and storm window, is going to depend on personal preference, good application practices with the old system, and condition of the existing window system.
Personally, I don't care if they put pixie dust in them, if it results in better U-values. :lol:
LOL - agreed. I was intrigued to see that
CO2 actually has a BETTER (lower) thermal conductivity quotient than Argon! Maybe we have a newfound use for all the excess CO2 we are frittering away into the atmosphere . . . ;-)
There is another article with good data calculating U-factors for single pane sash & storm stash combinations and comparing the data to that for thermopane windows. I had downloaded it to my computer, but it was several years ago and cannot find it. If I do I will post it somewhere.
Thanks for an invigorating discussion!