You need to know which venting type you need for your installation. (normally appliances are built for direct vent use or natural vent use and are not convertible)
This appliance is supplied as a direct vent but can be converted to a natural vented appliance. (Page 5)
Direct vent means the intake is directly connected to outside air source.
The manual describes it as such on page 3;
‘Direct Vent’ describes a sealed combustion system in which
incoming outside air for combustion and outgoing exhaust enter
and exit through two separate concentric passages within the
same sealed vent system. The system does not use room air to
support combustion. The Direct Vent system permits the gas appliance
to be vented directly to the outside atmosphere through
the side of the house or vertically through the roof. Conventional
venting systems (Natural Vent) take air from the room for combustion
and vent the exhaust vertically through the roof to the
atmosphere.
For direct vent the outlet is in the center (exhaust) and inlet is the larger pipe around the center.
You need the correct pipe and outdoor vent termination parts for intake and exhaust in the same vent.
Natural vent means the rising exhaust gasses lighter than air rise up the exhaust and intake air enters from inside the room. If the height isn't correct it will not create enough draft rising up the flue pipe to allow atmospheric air pressure to PUSH into intake. The intake used for natural vent is called a draft hood to get air from inside the building, with part number and explanation on page 5.
That is a very simple explanation of the differences. For example when connecting to the direct vent air intake / exhaust, you must follow guidelines to assure enough draft of rising gasses to allow enough air into the appliance. The chart on page 8 gives you the height and horizontal run that will work using direct vent mode.
Read entire installation instructions and ask before doing if you're not sure about anything.
https://woodstoves.net/documents/Vermont-Castings/stardance-dvtcs-7.pdf