Will 1.25 inch copper be a wise choice for plumbing the two pressurized storage tanks in tandom [boiler is Tarm Solo 60].
The rule of thumb on pipe gpm's is 1"= 8 gpm, 1.25" = 14 gpm, and 1.5" = 22 gpm. While the Solo 60 is rated at about 200,000 btu's, actual output, based on my experience with the Solo 40, is that, except for relatively brief peak burns or very high delta-T's, it will be unusual for you to achieve that output. I would expect your normal range of output to be 65-85% of rated capacity over a typical burn.
You say the storage will be in your out-building with the Tarm, so pipe length between the Tarm and storage will be very short. If you use 1.25" black steel pipe between the Tarm and the storage, assume total pipe equivalent length of 50', head loss is a little less than 3' at 14 gpm and a little less than 4' at 17 gpm. At these low head's you can use an inexpensive, low power consumption circulator without difficulty. A Taco 007 will move 17 gpm at 4' head and cost about $50 and use 80 watts. I mention Taco only because I have the circ charts stored on my computer for Taco, and it is easy for me to refer to them. Other brand circ should be satisfactory also.
Using a delta-T= 20F, 14 gpm = 140,000 btu, and 17 gpm = 170,000. Double this at delta-T = 40F. IMO, based on these assumptions, 1.25" plumbing between the Tarm and storage is very adequate. If you do have an occasional boiler idle, it will be brief and of little consequence. If you plan for consistent delta-T of less than 20F, then you need to move more water, which you can do with a higher capacity circ.
Plumbing between the out-building storage and the house, and plumbing within the house, is a different matter, and depends greatly on your heat loss calc for the house. Assuming 350' pipe equivalent length between the out-building and the manifold in the house, 1.25" pipe will have a little over 18' of head loss at 14 gpm, which is 140,000 btu at delta-T = 20F. A Taco 0011 may handle this, and a 0013 will more than handle this. Based on these assumptions, if your heat loss calc is 140,000 btu or less, 1.25" pipe should be OK.
If your house is low temp radiant, and you don't need water at 160F or greater, then you may be in an even better situation, because you can move higher temp water from storage and mix down at the house, the result being lower flow rates between storage and the house.
IMO your biggest decision is the plumbing between the out-building storage and the house, and you absolutely need to do a heat loss calc for the house to determine how many btu's, at what temp, and at what flow rate are required. With your distance, you do not want to be in a position of under-piping this pipe run based on your need; but on the other hand, it is very expensive to over-pipe if you don't need the capacity.
From your posts it sounds to me like you are winging it, but winging less and less as you learn more and more, just like many of the rest of us. With the Solo 40 I initially plumbed with 3/4" out of ignorance, and then replaced with 1". Fortunately, my plumbing run was short and the re-do was only a couple of hundred $$. 1" is plenty adequate for the Solo 40 in my situation, and yes, I do have an occasional idle at high return from stratified storage temps, but as mentioned, I regard that of no consequence.