At what boiler temp does this start to happen, also what boiler return temp? If it's as unnerving as you describe and not what we saw on the vid, but loud and spaced out more. Then you are boiling around the fire tubes, this will happen in my setup if:
1. High coal bed and very hot secondary burns
2. 190+ boiler temp
3. 180+ boiler return
If any of these changes and #3 is the one I can change quickly then the boiling stops.
I have measured a fixed 15gpm going through the boiler at all times, and 24psi at 190F boiler temp
I stop this by opening the zone valve for my large indirect via an aquastat set to 188F I set the boiler to idle at 194F to keep things from getting out of hand. It can drop the boiler return from 180 to 170 in a few seconds with a good cold slug of water mixing in the p/s loop. I mix the output from the indirect so there is no scalding potential anyway.
TS
Water will boil, or flash in a closed loop system anytime the pressure drops below the Vapor Pressure. In hydronic terms we call this cavitation. Several places to look for cavitration would be the circ pump. The pressure at the eye of the impeller can drop below the vapor pressure even with the system pressure at 12- 16 psi. Another common place cavitation occurs is a flow restriction or a partially closed valve somewhere. A balance valve, partially open ball valve and even a thermostatic 3 way valve can coax cavitation. Cavitation can sound like kettiling as the fluid is "boiling" at the impeller or restriction.
Also as the temperature of the water goes up, density drops, further compounding the potential for cavitation.
If you are sure you have wide open piping, no flow restriction or partially pluged "devices" try increasing the system pressure to 20 psi. Ideally you would want to adjust the expansion tank pre-charge also, but for a quick test, just bump the fill valve to 20 psi and see if the noise stops.
If that works, disconnect the expansion tank from the system pressure and pump it up to 20 psi. Now remember when you increase the fill and expansion tank pressure to match, ytou reduce the capacity of the expansion vessel. re-run the sizing formula to be sure the tank has the capacity to run at higher fill pressure. If the boiler pressure rises as the system heats, keep an eye on the pressure gauge, if it nears 28 psi or so, you need more expansion capacity. Reduce the pressure and increase or add an additional expansion tank.
Kettling or perculation as it is sometimes called is a common problem in copper tube boilers on DHW systems. A small coating of minerals reduces the heat transfer and you will get the perculation sound. It's like an old water heater that is filled with sediment, whan it heats up from the burner, you hear that boiling or perculation sound.
Same thing with an old tea kettle that is limed up, that poping noise or Rice Krispy sound is perculation, or cavitation.