The easiest option here is to:
(1) Buy an heat pump water heater (HPWH), which have really matured over the last several years, and use only about 33% as much energy as a conventional electric tank. I think CT has great incentives on HPWHs right now...might get the unit at a steep discount.
(2) Keep the boiler (for your desired backup) and leave it cold all summer.
Questions:
--On the HPWH, they can be loud, tall, and steal space heat from the room they are in. So you need to be able to site them somewhere where this will not be a problem. If you have a large family (or ar HW super users), you will want to get a 80 gal unit (IMO), which is more expensive than the stock 50 and 60 gal units, bc the recovery time when HW is used up can be a several hours. Some people fear that HPWHs don't pencil out in very cold climates. I am skeptical of that, esp since your space heat BTU are cheap (wood).
--Some older boilers will not be happy sitting cold for long periods (can rust out). If it is near the end of its life, or starting to leak a little, etc, this plan **might** hasten its demise. Conversely, most boilers will be aok with this.
--Some creative types think about putting the boiler and HPWH in series or something weird. Don't. I wouldn't even pay for the plumbing to have the option to switch between them. Just put in the HPWH, start burning some extra solar kWhs, and disconnect the boiler from the HW supply (ditching a mixing valve and other junk).
--Longer term, you could look at mini-splits for providing heating backup, or a whole house heat pump, depending on your climate. That and electric cars are common ways fo dealing with excess solar production. Of course CT elec rates are stupid expensive (my sis works at the elec company there) so that doesn't help elec pace heating.
--You can decide to run the boiler on standby in the winter or not, depending on several factors. My boiler burned more than a gallon of oil on standby per day. This had the effect of heating my house by 6-10°F above ambient. This drove up my AC bills a LOT (bc I would be running AC when it was not that hot out), but kept my furnace room (the wall of which was left uninsulated in 1960) nice and toasty. So obv you don't want that heat in the summer. But in the winter, if you leave the boiler off, your basement might get really cold, floors get colder, your wood consumption will go up, and the shoulder season might become longer. So, if you leave the boiler, you can decide to leave it hot on standby if any of those things are a problem, for a couple bucks a day. When I tore my boiler out, I ended up insulating that wall, and dropping a HVAC supply to that space. YMMV.