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If the rim diameter number is the same, it should fit, but you might get a wierd tire profile - I'd suggest looking at the tire maker's data to see what they say. You will probably need the width of the current rim to be able to tell.
The other thing to look out for is clearance inside the forks / fenders / etc, to make sure the wider profile won't cause any clearance problems - again the manufacturer info may be useful in terms of helping tell you the difference in the inflated dimensions of the new tire...
No, four inch is a big tire.
(Do a google image search for Surly Pugsley.)
A three inch will fit the forks well enough and probably the rim.
It'll give me extra flotation and shock absorbtion (rim saver),
and of course the "cool" factor.
You surely can find the largest tires you can fit (and clear the fork) from Surly's website. If you ever intend to use fenders, it probably will affect the clearance.