Let's say it achieves a 5% improvement in efficiency. How will you be quantifying the difference? Do you have the stove instrumented?
One interesting test would be to take a piece of material...firebrick, steel, or whatever - coat a section with this high E coating and coat a section right next to that with flat black spray paint. Let everything equalize for a good amount of time, then read both coatings with an IR temp gun.
Flat black spray paint generally has an emissivity around 0.95. If this stuff is higher than that, it would actually read warmer on the IR gun.