Starting from cold and measuring with a FlueGard internal probe about 18" above the stove I use the following startup procedure and it seems to be serving me pretty well:
Start Fire with CAT bypassed and air control wide open.
Burn with door open until roaring/rumbling.
Close the door at about 350-400F EGT.
Close the bypass (engage CAT) at 600F EGT.
Set air control to 1/4-3/8" open at 800F. (1/4" for larger fuel loads, 3/8" for smaller fuel loads)
Keep in mind, that I have 13' of single wall above the stove then about an 8' insulated chimney section, so there's more cooling/condensing in my system than on a system that is double/wall +insulated the whole way up, so this startup process may be overkill on target EGT's for your configuration, however, I would venture to bet that your wet elm is going to have a similar effect on the system as my large section of single wall, so you might be well served to target the same with that wood! I like starting out at this higher EGT as it ensures the chimney system is very well heated at the front end of the burn to minimize risk of condensed gases on the chimney/pipe. The Mansfield manual states that the stove will produce exhaust gases in the 500-1200F range and that this is normal. I figure, anything under 1000F at the meter 18" above the stove is probably fine, so targeting 800F leaves me a little room for accidental overshoot.
You'll find that in the time it took to run the stove up from 600F to 800F under that initial roaring combustion with the air control wide open, the little probe on the side of the stove will have jumped up to the "active" range. As long as you have a firebox full of roaring flames and EGT's above the stove measuring around 600F or better, I see no reason not to start sending it through the CATs. The probe on the side of the stove is not really in the direct path of exhaust while the cats are bypassed, so waiting for it to say "active" before engaging the cats is kinda backwards in my opinion. I have not had any issues engaging the cat in this manner and it sets everything in motion nice and quickly.
After setting the air control down to the desired rate for the remainder of the burn cycle, EGT's will steadily work their way down through the burn cycle from the initial 800F down to around 400F later in the coaling stages long after the flames in the box have gone out.
When the active flames in the box go out, you may hear the CAT "tink tink tink" during this part of the burn and the little gauge on the stove actually go jump up a fair bit during this part of the burn cycle. The remaining wood gases in the wood aren't enough to sustain fire in the box, but this is where the cats pick up the slack that secondary combustion can't do on its own. It's pretty awesome to observe!
That brings up an interesting point about this stove... If you ever hear it clink clink tink tinking, and see no flames in the box, but the temp probe on the side of the thing is getting up near or into the "too hot" zone, this means you have a whole bunch of combustion taking place in the cat. Your instinct at this point to correct the problem might be to close down the air control more. Doing this may actually make the problem worse. Opening up the air control to excite the fuel in the box to catch flame again will actually move that combustion back to the firebox/secondaries, and rapidly cool off the cat as a result. This also moves the heat output of the combustion back down lower in the box where it will have more opportunity to be transferred to the house. Alternatively, you can bypass the cat in this circumstance, but this will just send unburnt fuel up the stack, a waste of energy.
Over time, you'll learn what sort of fuel loads work best with what sort of air-control settings to burn through the fuel completely without getting into trouble at some mid-stage of the burn. I've found that in my setup, that 1/4-3/8" air control position that the stove manual suggests is a very reliable place to operate the stove when it has large to medium fuel loads. Smaller loads can get weird so be careful with that. Fully-closed should only be used to help draw down an over-excited active fire, leaving it in the fully-closed position through a burn cycle is likely to cause back-puffing and a premature transfer of combustion to the cats.
Good luck!
-Eric