You can make more trouble playing with an expansion tank, if you aren't careful.
It sounds like yours lost its air. For some reason. The main question is where did it go? By putting air back in, you gained expansion room. But what is your boiler/system pressure now? There needs to be a balance.
The proper way to set up a bladder expansion tank, and the system to go with it, if I can type it quickly without getting it wrong, is first to isolate it from the rest of the system. That means valving it off, maybe unhooking it. Then you would drain the water all out from it. That might require disconnection if your piping isn't valved & plumbed to allow it. Once it has no water in it, and the connection hole is open to the air, you would fill the air side to specd pressure. 12 is common. At the same time, you would get your boiler pressure right by either adding or draining water. Make it the same as the expansion tank. Do it with a cold boiler. (With it at the coldest temps it would see in a normal cycle of operating). Once you have the boiler and the air side of the expansion tank at same water & air pressure, you hook the expansion tank back up, then open it to the system.
With what you did, shortcuts may be possible. But when you added the air, you would also need to watch the water pressure on the boiler. And keep it the same as the air pressure. Either by adding or draining water. If you added air and the boiler pressure was a few pounds more than the air pressure, the tank would be full of or almost full of water and it would have no expansion capacity. That might be why you are still leaking.
EDIT: Also, if you don't use a low pressure air guage, your air pressure readings might not be accurate.