They are known for being accurate.
In case anyone misconstrued my previous comment - I am not saying that home-grade VOC sensors are inaccurate, but they are not traceable to some standard and cannot be calibrated. If I were to use my sensor data to prove a case in a court of law, it wouId not be credible or even admissible in court. Something that was traceable and calibrated would cost a lot more. However, I think it is accurate and provides me with the information I need.
Are we sure the VOCs aren't coming from the stove paint and/or some of the adhesives used in gaskets, etc.? I've been wondering about this myself.
That's a great question. The sensor I have doesn't give me any understanding of what the makeup of the VOCs actually are.
The stove has been well-cured at this point - there is no reason to suspect that paint or gaskets are off-gassing. The signature points clearly to the wood. And to be clear - I am not blaming the stove.
In fact, the VOCs could be coming from anything - non-stove interior product emissions (e.g., recently dry-cleaned clothes, formaldehyde from building products, etc.), from cooking activities, or from ripening/rotting foods. I've learned to recognize the signatures of other non-stove activities, and can separate that out from my readings.
Therefore, I have a pretty good handle on which VOC increases are caused by the stove and which are not. Some VOCs (i.e. from organic decomposition) I would not consider harmful. Others (from wood combustion) I do consider harmful at high enough levels for long enough periods and to be avoided, if possible.
I have been observing the VOC data over a long period of time to gain some understanding of the VOC signatures of various seasons and conditions. I know that my house has a <100 ppb VOC level by itself (which is quite good).
- There is an Amish steam sawmill about 3/4 of a mile south of me and down a hill - when I have a warm, wetter day (in the 40s, humid or rainy) and the wind is blowing from the south almost directly, my VOCs in the house go up (maybe they add 300-400 ppb to whatever baseline level I already have).
- I can see some early morning, afternoon, and evening pulses of VOC peaks on still air, warm, wetter days that seem to correlate with someone a 1/4 mile away and in the valley (I am just above the valley). They add anywhere from 200-500 ppb to whatever baseline levels I already have, and I can basically correlate it to looking out my front window and seeing their stovepipe smoking pretty well on a reload. The pulse durations are short.
- Sudden warming changes at the end of winter will cause VOC spikes for extended periods of time. I think this is because ground that is frozen is suddenly thawed and organic material in the ground starts to decompose, releasing VOCs.
- If I am cooking something on a higher heat with oil (I have an electric induction cooktop) or maybe with a lot of spices in it, sometimes I get VOC peaks even with the fan on and a kitchen window open. Same with baking something in the oven (I have an electric oven).
- I store winter squash, onions, garlic, shallots, and sweet potatoes over the winter in my basement. I cure squash indoors in the fall before moving it to the basement to store it for the winter. If a squash is going bad during the cure, my indoor VOC levels will spike a lot (maybe 1500-2000 ppb) and it is coming from the bad squash (which is sometimes hard to locate for another day or two until the mold appears). The bad squash gets tossed, and VOC levels return to <100 ppb.
The signature of my own wood stove (separated from all of the above, through trial and error) through various burn stages is as follows:
- No significant or noticeable increase in VOCs during reload - while this may seem counterintuitive, basically there is a lot air going up the chimney at this point and not a lot of wood breakdown into volatile chemicals at this point (there is a small bump in PM2.5, usually). Pattern holds whether door is open for a little longer than normal (i.e., door open to let in a little air during reload doesn't do anything to VOC levels)
- VOCs start to increase just before the active burn finishes (no more flaming, cat combustor fading to light orange, or orange only in a small part, or black everywhere). I can literally look at the slope of the VOC curve and predict in 10 minutes that the active burn will be over. That is usually when I now open the pipe damper (if it has been closed). If the burn startup was problematic (i.e., took a long time to reach cat combustion so wood likely a little wet) then I will probably open the air a little bit at this point as well.
- As the stove reaches the coaling phase, the VOCs start to increase and peak about 2 hours after the active burn has finished. Then they level out for 2-3 hours (depending on wood species). For info, it takes about 3 hours for my heat-recovery ventilator to completely change all the air in the house once.
- VOCs decrease at the end of the coaling (coals burned down) OR stay elevated AND/OR have a second bump up in VOC levels (probably due to a piece of wood shifting and opening new surfaces for combustion).
Other observations:
- Use of pipe damper doesn't seem to have any impact (surprising to me) as long as I open it fully at the end of the active burn.
- Lower flue pipe temperatures probably mean less draft and therefore more likelihood that VOCs are staying in the stove longer and getting out somewhere (through gaskets, or through the flue pipe connections).
- The denser the wood (e.g. hickory) the more VOCs I'll have at peak and the longer the peak will take to return to normal levels. Not surprising - more weight = more volatiles.
For a load with wood that is optimally dry, then stage 1 has zero increase in VOCs, stage 2 will have a very slight slope and lasts longer, stage 3 might mean a VOC peak of only 250-350 ppb (very acceptable to me) for a shorter time, and stage 4 shows the VOC decrease back down to ~100 ppb by time of next reload (usually 9-10 hours into a 12 hour burn/reload cycle).
For a load with some wood that is not optimally dry (but not 1-year wood or obviously wood I should not burn), the stage 1 might show a VOC increase to 250-300 ppb, then stage 2 has a steep slope, stage 3 might peak at 1000 ppb, and stage 4 might decrease slowly or not at all and/or may have a bump in the VOCs late in the coaling and VOCs will not return to house background levels of ~100 ppb. I attribute this signature to wood that is not really ready for coaling by the time the active burn has completed and it is smoldering. In fact, I can look into the stove and see pieces of wood that are well-charred and coaled, but not falling apart (still together). To me, this is a sign of wood that still had too much moisture in the far interior of the wood and that moisture meant incomplete combustion during the active burn and now smoldering.
This is what I am going to try during the off-season to see if it improves VOC levels during the next burning season.
- I should have even better wood next year - a) better top covers that don't leak, starting last spring; b) wood spaced farther apart in the stacks: and c) 3-year dried wood in the stacks that never spent any time on the ground). Optimally dry wood should really help the most (my belief).
- More wood of similar size (meaning some of my really big pieces will get resplit, and maybe redried for another year after that). One piece of wood a lot bigger than all others means its combustion will probably be incomplete when active burn is finished.
- I am going to remove and reinstall my double-wall black pipe that connects in to the back of the stove and to the double-wall chimney pipe vertical run. Goal is to reduce the horizontal run by 6" (increase the draft on startup and also during late coaling) and get the pipe damper a little closer to the stove. I may even try adding some high-temperature caulk to the the connections (though Selkirk never says this is required in any of their installation manuals).
- I don't like how not tightly the double-wall black pipe connects to the back of the stove. I will definitely try sealing this better with high temperature caulk. This is probably a no-brainer and I should have done this before.
- I read something from someone (Todd, or BeGreen maybe?) in a different post about using some sort of soapstone dust mix to create a flexible mortar for the joints on the inside of the stove. I'll probably try that also.
- I am going to buy a manometer to measure the balance of my HRV system. I suspect that it is also not balanced correctly and is de-pressurizing the house slightly, which might exacerbate any issues I've been experiencing during less than optimal wood loads.
Stay tuned.