Was the samsonite luggage testing Gorilla drunk when he wire that mess up?
You need to get that junk off the boiler steam jacket quick
!!
SO
1. you have three Valiant zone valves
2. you have one Grundfos circulator in the lower left corner of the boiler
3. you have what looks like a 30 plate heat exchanger
4. you have a bladder type expansion tank
5. you have a motorized damper in the flue stack to hold in the heat from the steam chest of the boiler
6. If that is the blow off valve on the left middle side of the picture that is an absolute NO NO it has to be in top of the steam chest or a side tapping at the top of the steam chest.
You can forget about your insurance company paying a damage claim if you have a fire that is caused by the gas boiler.
You need an electrician for at least two days and a good plumber for 2 days to rip everything out and start all over again to fix that snake cluster****.
The sooner you get an electrician the better to fix that mess the better as you could have a fire and burn up the control wiring
Both your county plumbing and county electrical inspector would fail your heating set up and attach a failed inspection tag for your heating appliance and you would not, (ABSOLUTELY WILL NOT) have heat in the home until the system is repaired by a licensed plumber and licensed electrician.