Chimney smell

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By chimney, do you mean the stovepipe? Is this single-wall black metal or a double-wall stove pipe? What is too hot?
 
Sounds like painted stove pipe. Depends on the pipe, the paint and how hot it's getting. Most do smell when too hot.
 
My chimney produces an odor when it gets too hot. My stove is a heritage 1 8021. My chimney goes straight up.
Also how hot is to hot?