The end switch on that valve breaks open within seconds of the heat call going away, then about 5-7 seconds for the valve to spring close and seal. I suspect the pump, in fluid stops spinning almost instantly.
I'm not clear on why a pump and a zone valve? A pump with an integral check would prevent ghost flow.
Circulators can pump towards or away from that purger without a problem.
Unless that gauge drops to 0 or lower
when the pump is running you are not pulling a sub atmospheric condition and air will not enter. To prove that buy a 1/2 cap and screw it on the discharge of the Spirovent.
Most common is a pump, and a float type air vent on a tee at the return side of the coil, make it the high point to catch any air that migrates to the coil.
High point, float type air vents are found on air handlers, radiators, radiant manifolds and on top of most cast iron boilers.
That Sprio can actually hold a small amount of air, until enough of a bubble causes the float inside to drop far enough and spit the air out. It may well be holding not expelling your rouge air bubble, and it is not at the high point at the coil, near the zone valve.
Get rid of the zone valve, make that ell a tee and add a float vent there, that should solve your problems once and for all.