This topic has come up in the past. One question is whether the silicone boot is UL approved and accepted by the chimney pipe mfg. for this application. You may find this thread helpful.
https://www.hearth.com/talk/threads/silicone-roof-jack-with-class-a-chimney.43014/
https://www.hearth.com/talk/threads/silicone-roof-jack-with-class-a-chimney.43014/