when there's no flame you are burning the same particles in the cat that can condense on the wall....I think burning off condensed creosote in the firebox doesn't factor in the smells outside.
Creosote is formed when wood smoke is cooled, so I think that different chemical compounds may be formed, just as temperature differences can alter other chemical reactions. I've seen "wood tar" mentioned as a component of creosote. So when creo burns, I think it can produce a different odor than the combustion of just wood. I don't have a degree in chemistry, though. 😏
In a cold stove, when creosote in the box is thick and wet, it I get big flames going in the box and begin burning the creo
before closing the bypass, I get big clouds of thick, dark, acrid smoke. It's not just steam from the creo drying out, and it's a totally different (terrible) smell than the smoke I get from a cold start with only wood in a clean box. That would seem to refute the theory that
"chemistry of the combustion of those gases that is different in a secondary jet flame than in a catalytic converter" is the only thing responsible for odor differences.
Even after you close the bypass, the burning cat can't catch/burn all the creo smoke. That's why I think it's different than plain wood smoke. Granted, it's possible to blow unburned wood smoke through the cat as well, by having the air open too much; The smoke doesn't get enough residence time in the cat to get burned. But the creo smoke makes it through the cat, even when you don't have the air open very far at all. And even at the point that the creo smoke is no longer present, the stench still is, to some extent.
I'm really surprised that you haven't noticed this phenomenon, since you burn a BK, the undisputed King of black-glass creo production. 😆
I don't think we're going to get any input from anyone that is in this thread about what they've observed with creo, since we are off track from the original topic. I'd need to start a "Stinky Creo Smoke" thread. 😏 But I
have seen it mentioned in several threads..
Next time I make it out to Long Island, I'll set up your stove for a nice, stinky creo fire, and we'll smoke-bomb the 'hood until your neighbors emerge, sneezing and wheezing, eyes watering and begging for mercy. 😆