Tokelau Island Chain is the first solar power country. The link below is a longer than some of the others I have read, but the BBC also carried this story. They say they've built enough solar panels and storage batteries to supply 150% of their current electric needs. Use coconuts to make biofuels to supplement other needs. Can't make this stuff up.
http://inhabitat.com/pacific-tokelau-island-chain-becomes-worlds-first-solar-powered-nation/
http://inhabitat.com/pacific-tokelau-island-chain-becomes-worlds-first-solar-powered-nation/