I think I'm the only one here who's been running one of each, for an easy comparison in the same weather, house, wood, etc. Most have only tried one or the other in their Ashfords, as only the Steelcat was available originally, and the model isn't all that old.
If you have a tall pipe, strong draft, or ever had issues with your steelcat clogging, then ceramic is the clear winner. But if you're the type to throw the door open on a glowing-hot cat, then the steelcat is more forgiving to thermal shock.
Don't believe anyone who tells you one goes active quicker or stays active longer, it's complete BS, or the differences so small in the grand scheme of burn time that any difference is completely trivial. You've got a 700,000 BTU load of wood raging at 1000°F during the bypass phase, fighting to warm up several hundred pounds of cool metal and brick… and people are gullible enough to actually believe a few ounces of combustor mass makes some meaningful difference in light-off time, in the face of that?
If it makes any difference, which I have not been able to determine myself, it must be so small as to be meaningless to actual operation.
That said, there are two coatings that have been made for these cats over the years. I believe all cats supplied through BK use the newer coating (called "B3" for "beta 3" when I got mine back around 2018, but I believe they're now called "V3" for "version 3"), and that really does seem to make a difference in how early you can light off and how low you can burn. I think it may support reburn at a lower temperature than the original coating, as I do get fast and easier light off on my combust or with this coating.
I believe that if you buy your combustor thru your BK dealer, you get the new coating, but most aftermarket retailers are probably still selling the older chemistry. Search for “coating” by BKVP, for the few comments he has been able to make about this in the past, but understand that regulations limit exactly what he can say about replacement combustors.
Even this is not critical, I’ve yet to try a combustor in my BK Ashford 30 that didn’t work just fine, excepting the clogging issues I had with a steelcat on my taller chimney.