@arnermd
I still would like to see your data when you do a burn with bark removed from your wood. Here is my logical reasoning:
Bark is harder (on most species) to light and burn. I know there are exceptions, so if you do this test please mention what type of wood your burn is on. Bark will also require a higher combustion temperature to burn and makes lots of smoke.
this could be why you are see late spikes in cat temps over time.
Or, its the wood in the middle of your stove/top of stove that is baking as the lower logs burn and by the time the higher up logs ignight, they off gas later in your burn cycle.
My experience in testing:
I would load a hot box of pine/white oak mix with pine lower in the box and oak higher up. My logic: the pine with ignight, turn into coals and the oak will slow cook for my longer burn cycles.
My smoke out the stack is minimal on these. Then I have tried throwing some bark only chunks on the very top and that bark stays unburned for a few hours. It won't ignight or burn until the oak burns down and then BOOM the bark will catch and dump tons of smoke into the fire box and overwhelms my cat. When this happens I get lots of smoke out of the chimney even when all my temps are nice and hot.
I think bark is the key in cat temp issues.
Thoughts?